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Issue 3, 2015
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Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines

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Abstract

A Cu(I)-catalyzed denitrogenative transannulation reaction of pyridotriazoles with terminal alkynes en route to indolizines was developed. Compared to the previously reported Rh-catalyzed transannulation reaction, this Cu-catalyzed method features aerobic conditions and a much broader scope of pyridotriazoles and alkynes.

Graphical abstract: Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines

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Publication details

The article was received on 01 Nov 2014, accepted on 03 Jan 2015 and first published on 05 Jan 2015


Article type: Edge Article
DOI: 10.1039/C4SC03358B
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Citation: Chem. Sci., 2015,6, 1928-1931
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    Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines

    V. Helan, A. V. Gulevich and V. Gevorgyan, Chem. Sci., 2015, 6, 1928
    DOI: 10.1039/C4SC03358B

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