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Issue 65, 2015
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Base catalyzed sustainable synthesis of phenyl esters from carboxylic acids using diphenyl carbonate

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Abstract

Phenyl esters were obtained in moderate to high yields by reaction of aliphatic and aromatic carboxylic acids with one equivalent of diphenyl carbonate in the presence of catalytic amounts of tertiary amine bases, such as DBU, TBD and DMAP under neat conditions at elevated temperatures (>100 °C).

Graphical abstract: Base catalyzed sustainable synthesis of phenyl esters from carboxylic acids using diphenyl carbonate

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Publication details

The article was received on 29 May 2015, accepted on 11 Jun 2015 and first published on 11 Jun 2015


Article type: Communication
DOI: 10.1039/C5RA10206E
Citation: RSC Adv., 2015,5, 53155-53160
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    Base catalyzed sustainable synthesis of phenyl esters from carboxylic acids using diphenyl carbonate

    O. Kreye and M. A. R. Meier, RSC Adv., 2015, 5, 53155
    DOI: 10.1039/C5RA10206E

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