Issue 52, 2015
From the journal:

RSC Advances

Iodine-catalyzed C–H/S–H oxidative coupling: from 1,3-diketones and thiophenols to β-dicarbonyl thioethers†

Hao Cao,‡ab   Jiwen Yuan,‡b   Chao Liu, ORCID logo b   Xinquan Hu*a  and  Aiwen Lei*bc  

* Corresponding authors

a College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, China
E-mail: xinquan@zjut.edu.cn

b College of Chemistry and Molecular Sciences, The Institute for Advanced Studies (IAS), Wuhan University, Wuhan, Hubei 430072, P. R. China
E-mail: aiwenlei@whu.edu.cn

c National Research Center for Carbohydrate Synthesis, Jiangxi Normal University, Nanchang 330022, Jiangxi, P. R. China

Abstract

A novel method on iodine-catalyzed oxidative coupling between 1,3-diketones and thiophenols to form β-dicarbonyl thioethers was developed. The C–S bond was supposed to be formed via a radical substitution pathway instead of the usual nucleophilic substitution one.

Graphical abstract: Iodine-catalyzed C–H/S–H oxidative coupling: from 1,3-diketones and thiophenols to β-dicarbonyl thioethers

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Article information

DOI
https://doi.org/10.1039/C5RA04906G
Article type
Communication
Submitted
19 Mar 2015
Accepted
24 Apr 2015
First published
24 Apr 2015

RSC Adv., 2015,5, 41493-41496

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Iodine-catalyzed C–H/S–H oxidative coupling: from 1,3-diketones and thiophenols to β-dicarbonyl thioethers

H. Cao, J. Yuan, C. Liu, X. Hu and A. Lei, RSC Adv., 2015, 5, 41493 DOI: 10.1039/C5RA04906G

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