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Issue 52, 2015
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Iodine-catalyzed C–H/S–H oxidative coupling: from 1,3-diketones and thiophenols to β-dicarbonyl thioethers

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Abstract

A novel method on iodine-catalyzed oxidative coupling between 1,3-diketones and thiophenols to form β-dicarbonyl thioethers was developed. The C–S bond was supposed to be formed via a radical substitution pathway instead of the usual nucleophilic substitution one.

Graphical abstract: Iodine-catalyzed C–H/S–H oxidative coupling: from 1,3-diketones and thiophenols to β-dicarbonyl thioethers

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Publication details

The article was received on 19 Mar 2015, accepted on 24 Apr 2015 and first published on 24 Apr 2015


Article type: Communication
DOI: 10.1039/C5RA04906G
Citation: RSC Adv., 2015,5, 41493-41496
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    Iodine-catalyzed C–H/S–H oxidative coupling: from 1,3-diketones and thiophenols to β-dicarbonyl thioethers

    H. Cao, J. Yuan, C. Liu, X. Hu and A. Lei, RSC Adv., 2015, 5, 41493
    DOI: 10.1039/C5RA04906G

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