Ionothermal synthesis of a new three-dimensional manganese(II) phosphate with DFT-zeotype structure

Yongke He; Yan Yan; Junbiao Wu; Xiaowei Song

doi:10.1039/C5RA01350J

Ionothermal synthesis of a new three-dimensional manganese(II) phosphate with DFT-zeotype structure

Yongke He,^a^b Yan Yan,^a Junbiao Wu^a and Xiaowei Song*^a

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* Corresponding authors

^a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China
E-mail: xiaoweisong@jlu.edu.cn
Fax: +86-431-85168582
Tel: +86-431-85168582

^b Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, P. R. China

Abstract

A new manganese phosphate |H₃N(CH₂)₂NH₃|[Mn₂P₂O₈] (denoted as JIS-14), has been ionothermally synthesized by using eutectic mixtures as the solvent and template-delivery agent, which in situ yields ethylene diammonium cations (en²⁺) acting as the template. JIS-14 is the first example of manganese phosphate with 4-connected zeolite topology and exhibits a DFT-zeotype framework built up from the strict alternation of MnO₄ and PO₄ tetrahedra forming 3D 8-ring channels. Protonated en²⁺ cations locate in the channels compensate the negative charges of the inorganic framework. Magnetic measurements reveal that weak antiferromagnetic interaction exists in JIS-14.

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Publication details

The article was received on 23 Jan 2015, accepted on 16 Feb 2015 and first published on 16 Feb 2015

Article type: Communication

DOI: 10.1039/C5RA01350J

Citation: RSC Adv., 2015,5, 21019-21022

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Ionothermal synthesis of a new three-dimensional manganese(II) phosphate with DFT-zeotype structure

Y. He, Y. Yan, J. Wu and X. Song, RSC Adv., 2015, 5, 21019
DOI: 10.1039/C5RA01350J
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Ionothermal synthesis of a new three-dimensional manganese(II) phosphate with DFT-zeotype structure

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Ionothermal synthesis of a new three-dimensional manganese(II) phosphate with DFT-zeotype structure

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