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Issue 31, 2015
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O2-mediated C(sp2)–X bond oxygenation: autoxidative carbon–heteroatom bond formation using activated alkenes as a linkage

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Abstract

Autoxidative carbon–heteroatom bond formation using activated alkenes as a linkage is described. Heteroatom (O, S) nucleophiles could be transformed into different kinds of valuable β-keto compounds via an O2-mediated C(sp2)–X bond oxygenation process, without using any external organic oxidants or metal catalysts.

Graphical abstract: O2-mediated C(sp2)–X bond oxygenation: autoxidative carbon–heteroatom bond formation using activated alkenes as a linkage

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Publication details

The article was received on 26 Dec 2014, accepted on 16 Feb 2015 and first published on 19 Feb 2015


Article type: Communication
DOI: 10.1039/C4RA17106C
Citation: RSC Adv., 2015,5, 24494-24498
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    O2-mediated C(sp2)–X bond oxygenation: autoxidative carbon–heteroatom bond formation using activated alkenes as a linkage

    Q. Lu, J. Chen, C. Liu, Z. Huang, P. Peng, H. Wang and A. Lei, RSC Adv., 2015, 5, 24494
    DOI: 10.1039/C4RA17106C

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