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Issue 21, 2015
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Important factors for effective use of carbon nanotube matrices in electrochemical capacitor hybrid electrodes without binding additives

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Abstract

Various capacitive particles are currently available for use in electrochemical capacitors, but their electrical conductivities are typically low and require enhancement. Carbon nanotube (CNT) matrices can be used to fabricate self-supporting electrodes without binding or conducting additives. Herein, liquid dispersion and subsequent vacuum filtration were used to prepare thick (∼100 μm) hybrid electrodes of activated carbon (AC) and CNTs. Factors including CNT type, AC particle size, solvent, and surfactant strongly affected the capacitance and rate performance of the hybrid electrodes. Different solvents and types of CNTs were best suited for pure CNT electrodes and AC–CNT hybrid electrodes; single-wall CNTs (SWCNTs) with a strong dispersant produced CNT electrodes with the best performance among pure CNT electrodes. Meanwhile, few-wall CNTs (FWCNTs) with a weak dispersant produced AC–CNT hybrid electrodes with the best performance among hybrid electrodes. Addition of 10 wt% FWCNTs to AC yielded a self-supporting hybrid electrode with improved performance (132 F g−1, 58 F cm−3, 0.70 F cm−2 at 100 mV s−1) compared with that of a conventional AC electrode with conducting and binding additives (74 F g−1, 26 F cm−3, 0.60 F cm−2 at 100 mV s−1), and a pure electrode of expensive SWCNTs (52 F g−1, 26 F cm−3, 0.26 F cm−2 at 100 mV s−1).

Graphical abstract: Important factors for effective use of carbon nanotube matrices in electrochemical capacitor hybrid electrodes without binding additives

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Publication details

The article was received on 17 Dec 2014, accepted on 29 Jan 2015 and first published on 29 Jan 2015


Article type: Paper
DOI: 10.1039/C4RA16560H
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Citation: RSC Adv., 2015,5, 16101-16111
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    Important factors for effective use of carbon nanotube matrices in electrochemical capacitor hybrid electrodes without binding additives

    R. Quintero, D. Y. Kim, K. Hasegawa, Y. Yamada, A. Yamada and S. Noda, RSC Adv., 2015, 5, 16101
    DOI: 10.1039/C4RA16560H

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