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Issue 8, 2015
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Autoinductive thiolation/oxygenation of alkenes at room temperature

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Abstract

A new reaction for O2 fixation is rationally demonstrated, in which radical thiolation/oxygenation of activated alkenes proceeds spontaneously at room temperature with no need for any additives. EPR and operando IR experiments revealed that O2 serves as the initiator to trigger this radical reaction and that autoinductive processes are the critical factor to drive the reaction.

Graphical abstract: Autoinductive thiolation/oxygenation of alkenes at room temperature

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Publication details

The article was received on 29 Mar 2015, accepted on 07 May 2015 and first published on 07 May 2015


Article type: Research Article
DOI: 10.1039/C5QO00102A
Citation: Org. Chem. Front., 2015,2, 908-912
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    Autoinductive thiolation/oxygenation of alkenes at room temperature

    Q. Lu, H. Wang, P. Peng, C. Liu, Z. Huang, Y. Luo and A. Lei, Org. Chem. Front., 2015, 2, 908
    DOI: 10.1039/C5QO00102A

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