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Issue 2, 2015
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Transition metal-catalyzed direct remote C–H functionalization of alkyl groups via C(sp3)–H bond activation

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Abstract

This review is focused on the recent advances in the transition metal-catalyzed direct remote C–H-functionalization of alkyl groups via C(sp3)–H bond activation. In general, carboxamide/ester-chelated β-functionalization reactions are summarized, which mainly include direct β-arylation, β-alkylation, β-alkynylation, etc. Additionally, some biologically interesting architectures are constructed by using these direct β-functionalization reactions.

Graphical abstract: Transition metal-catalyzed direct remote C–H functionalization of alkyl groups via C(sp3)–H bond activation

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Publication details

The article was received on 24 Jul 2014, accepted on 28 Nov 2014 and first published on 01 Dec 2014


Article type: Review Article
DOI: 10.1039/C4QO00207E
Citation: Org. Chem. Front., 2015,2, 169-178
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    Transition metal-catalyzed direct remote C–H functionalization of alkyl groups via C(sp3)–H bond activation

    G. Qiu and J. Wu, Org. Chem. Front., 2015, 2, 169
    DOI: 10.1039/C4QO00207E

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