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Issue 3, 2015
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8-(2-Cycloalkylphenylimino)-5,6,7-trihydro-quinolylnickel halides: polymerizing ethylene to highly branched and lower molecular weight polyethylenes

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Abstract

Cycloalkyl-modified 8-arylimino-5,6,7-trihydroquinolylnickel pre-catalysts, activated with either MAO or Et2AlCl, are highly active for the polymerization of ethylene into branched polyethylene waxes with narrow polydispersity.

Graphical abstract: 8-(2-Cycloalkylphenylimino)-5,6,7-trihydro-quinolylnickel halides: polymerizing ethylene to highly branched and lower molecular weight polyethylenes

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Publication details

The article was received on 15 Oct 2014, accepted on 08 Jan 2015 and first published on 12 Jan 2015


Article type: Research Article
DOI: 10.1039/C4QI00162A
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Citation: Inorg. Chem. Front., 2015,2, 223-227
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    8-(2-Cycloalkylphenylimino)-5,6,7-trihydro-quinolylnickel halides: polymerizing ethylene to highly branched and lower molecular weight polyethylenes

    Z. Sun, E. Yue, M. Qu, I. V. Oleynik, I. I. Oleynik, K. Li, T. Liang, W. Zhang and W. Sun, Inorg. Chem. Front., 2015, 2, 223
    DOI: 10.1039/C4QI00162A

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