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Issue 38, 2015
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Amide-bridged ladder poly(p-phenylene): synthesis by direct arylation and π-stacked assembly

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Abstract

Amide-bridged ladder poly(p-phenylene) was synthesized in two steps, through the polycondensation of aromatic diamines and dicarboxylic acid derivatives followed by palladium-catalyzed intramolecular direct arylation. The π-stacked assembly of the polymer in solution was investigated along with the single crystal X-ray structure analysis of a model oligomer.

Graphical abstract: Amide-bridged ladder poly(p-phenylene): synthesis by direct arylation and π-stacked assembly

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Publication details

The article was received on 23 Jul 2015, accepted on 07 Aug 2015 and first published on 11 Aug 2015


Article type: Communication
DOI: 10.1039/C5PY01154J
Citation: Polym. Chem., 2015,6, 6792-6795
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    Amide-bridged ladder poly(p-phenylene): synthesis by direct arylation and π-stacked assembly

    K. Takagi, R. Kato, S. Yamamoto and H. Masu, Polym. Chem., 2015, 6, 6792
    DOI: 10.1039/C5PY01154J

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