Issue 25, 2015
From the journal:

Organic & Biomolecular Chemistry

meso-Tetraphenylporphyrin with a pi-system extended by fusion with anthraquinone†

Mikhail A. Filatov,*ab   Ernesta Heinrich,a   Katharina Landfestera  and  Stanislav Baluschevacd  

* Corresponding authors

a Max Planck Institute for Polymer Research, Ackermannweg 10, D-55128 Mainz, Germany
Fax: +496131379100

b Institute of Polymers, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., block 103-A, BG - 1113 Sofia, Bulgaria
E-mail: filatov@polymer.bas.bg

c Optics and Spectroscopy Department, Faculty of Physics, Sofia University “St. Kliment Ochridski”, 5 James Bourchier, 1164 Sofia, Bulgaria

d Freiburg Institute for Advanced Studies (FRIAS), Albert-Ludwigs-Universität Freiburg, Albertstraße 19, D-79104 Freiburg, Germany

Abstract

Fusion with a 9,10-anthraquinone moiety was achieved to extend porphyrin's π-system. A bridged dihydroisoindole derivative was used to prepare the corresponding meso-tetraphenyltetraanthraquinonoporphyrin (Ph4TAQP) via a thermal retro-Diels–Alder reaction. The basic optical properties of the prepared new anthraquinonoporphyrin and its complexes with Zn and Pd were studied.

Graphical abstract: meso-Tetraphenylporphyrin with a pi-system extended by fusion with anthraquinone

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Article information

DOI
https://doi.org/10.1039/C5OB00884K
Article type
Paper
Submitted
01 May 2015
Accepted
14 May 2015
First published
14 May 2015
This article is Open Access
Creative Commons BY license

Org. Biomol. Chem., 2015,13, 6977-6983

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meso-Tetraphenylporphyrin with a pi-system extended by fusion with anthraquinone

M. A. Filatov, E. Heinrich, K. Landfester and S. Baluschev, Org. Biomol. Chem., 2015, 13, 6977 DOI: 10.1039/C5OB00884K

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