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Issue 8, 2015
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Copper-catalyzed oxidative alkenylation of thioethers via Csp3–H functionalization

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Abstract

A novel copper-catalyzed oxidative alkenylation of thioethers via Csp3–H functionalization to construct allylic thioethers is first demonstrated. Different 1,1-disubstituted olefins could cross-couple with thioethers to generate the corresponding alkenylation products in moderate to excellent yields. This reaction is supposed to proceed via a radical process.

Graphical abstract: Copper-catalyzed oxidative alkenylation of thioethers via Csp3–H functionalization

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Publication details

The article was received on 08 Dec 2014, accepted on 22 Dec 2014 and first published on 22 Dec 2014


Article type: Communication
DOI: 10.1039/C4OB02564D
Citation: Org. Biomol. Chem., 2015,13, 2264-2266
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    Copper-catalyzed oxidative alkenylation of thioethers via Csp3–H functionalization

    H. Cao, D. Liu, C. Liu, X. Hu and A. Lei, Org. Biomol. Chem., 2015, 13, 2264
    DOI: 10.1039/C4OB02564D

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