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Issue 40, 2015
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Pd2Au36(SR)24 cluster: structure studies

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Abstract

The location of the Pd atoms in Pd2Au36(SC2H4Ph)24, is studied both experimentally and theoretically. X-ray photoelectron spectroscopy (XPS) indicates oxidized Pd atoms. Palladium K-edge extended X-ray absorption fine-structure (EXAFS) data clearly show Pd–S bonds, which is supported by far infrared spectroscopy and by comparing theoretical EXAFS spectra in R space and circular dichroism spectra of the staple, surface and core doped structures with experimental spectra.

Graphical abstract: Pd2Au36(SR)24 cluster: structure studies

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Publication details

The article was received on 29 Jun 2015, accepted on 14 Sep 2015 and first published on 22 Sep 2015


Article type: Paper
DOI: 10.1039/C5NR04324G
Author version available: Download Author version (PDF)
Citation: Nanoscale, 2015,7, 17012-17019
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    Pd2Au36(SR)24 cluster: structure studies

    B. Zhang, S. Kaziz, H. Li, D. Wodka, S. Malola, O. Safonova, M. Nachtegaal, C. Mazet, I. Dolamic, J. Llorca, E. Kalenius, L. M. Lawson Daku, H. Hakkinen, T. Bürgi and N. Barrabés, Nanoscale, 2015, 7, 17012
    DOI: 10.1039/C5NR04324G

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