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The ene-process with unsaturated ketones was catalyzed by Lewis acids such as bismuth or indium triflates. Unlike aldehydes, the reverse ene-process occurs with ketones, resulting in incomplete conversions, as shown by control experiments and analysis by ESI-MS.
P. Tremel, C. Iacobucci, L. Massi, S. Olivero, J.-F. Gal and E. Duñach, New J. Chem., 2015, 39, 7453 DOI: 10.1039/C5NJ01286D
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