Variation of through-space magnetic response properties upon the formation of cation–π interactions: a survey of [Ag(η-CH2CH2)3]+via DFT calculations

J. Camacho Gonzalez; C. Morales-Verdejo; A. Muñoz-Castro

doi:10.1039/C5NJ00475F

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Variation of through-space magnetic response properties upon the formation of cation–π interactions: a survey of [Ag(η-CH₂CH₂)₃]⁺via DFT calculations†

J. Camacho Gonzalez,^a C. Morales-Verdejo

^b and A. Muñoz-Castro*^c

Author affiliations

* Corresponding authors

^a Departamento de Estudios Pedagógicos, Facultad de Filosofía y Humanidades, Universidad de Chile, Av. Capitán Ignacio Carrera Pinto 1025, Ñuñoa Santiago de, Chile
E-mail: jpcamacho@uchile.cl

^b Universidad Bernardo O Higgins, Departamento de Ciencias Químicas y Biológicas, General Gana 1780, Santiago, Chile

^c Dirección de Postgrado e Investigación, Universidad Autonoma de Chile, Carlos Antunez 1920, Santiago, Chile
E-mail: alvaro.munoz@uautonoma.cl

Abstract

[Ag(η-CH₂CH₂)₃]⁺ is a prototypical metal–olefin complex displaying cation–π interactions. Herein, we describe the through-space magnetic response to better understand the influence of the metallic center on the organic ligands. The analysis reveals the short- and long-range anisotropic effects produced by Ag⁺, which influence the C₂H₄ ligands.

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Article information

DOI: https://doi.org/10.1039/C5NJ00475F
Article type: Letter
Submitted: 25 Feb 2015
Accepted: 21 Apr 2015
First published: 23 Apr 2015

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New J. Chem., 2015,39, 4244-4248

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Variation of through-space magnetic response properties upon the formation of cation–π interactions: a survey of [Ag(η-CH₂CH₂)₃]⁺via DFT calculations

J. Camacho Gonzalez, C. Morales-Verdejo and A. Muñoz-Castro, New J. Chem., 2015, 39, 4244 DOI: 10.1039/C5NJ00475F

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