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Issue 9, 2015
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Catalytic intramolecular carbonyl–ene reaction with ketones: evidence for a retro–ene process

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Abstract

The ene-process with unsaturated ketones was catalyzed by Lewis acids such as bismuth or indium triflates. Unlike aldehydes, the reverse ene-process occurs with ketones, resulting in incomplete conversions, as shown by control experiments and analysis by ESI-MS.

Graphical abstract: Catalytic intramolecular carbonyl–ene reaction with ketones: evidence for a retro–ene process

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Publication details

The article was received on 21 May 2015, accepted on 22 Jul 2015 and first published on 23 Jul 2015


Article type: Paper
DOI: 10.1039/C5NJ01286D
Author version available: Download Author version (PDF)
Citation: New J. Chem., 2015,39, 7453-7458
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    Catalytic intramolecular carbonyl–ene reaction with ketones: evidence for a retro–ene process

    P. Tremel, C. Iacobucci, L. Massi, S. Olivero, J.-F. Gal and E. Duñach, New J. Chem., 2015, 39, 7453
    DOI: 10.1039/C5NJ01286D

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