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Issue 9, 2015
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Interaction of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) with CoX2 (X = Cl, Br) in water: trapping of new self-assembled water–chloride/bromide clusters in a [Co(bpca)2]+ host (bpca = bis(2-pyrimidylcarbonyl)amidate anion)

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Abstract

2D polymeric water–chloride/bromide sheets comprising a unique pentagon-like dichloride/dibromide-trihydrate cluster in the solid state have been observed as [Co(bpca)2]+ (bpca = bis(2-pyrimidylcarbonyl)amidate anion) counterions. Both compounds were obtained by the reaction of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) with CoX2 (X = Cl, Br) in water. Solid-state multinuclear magnetic resonance spectroscopy and XRD provide insight into the structures.

Graphical abstract: Interaction of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) with CoX2 (X = Cl, Br) in water: trapping of new self-assembled water–chloride/bromide clusters in a [Co(bpca)2]+ host (bpca = bis(2-pyrimidylcarbonyl)amidate anion)

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Publication details

The article was received on 04 May 2015, accepted on 02 Jul 2015 and first published on 02 Jul 2015


Article type: Paper
DOI: 10.1039/C5NJ01125F
Author version available: Download Author version (PDF)
Citation: New J. Chem., 2015,39, 7147-7152
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    Interaction of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) with CoX2 (X = Cl, Br) in water: trapping of new self-assembled water–chloride/bromide clusters in a [Co(bpca)2]+ host (bpca = bis(2-pyrimidylcarbonyl)amidate anion)

    D. A. Safin, P. M. J. Szell, A. Keller, I. Korobkov, D. L. Bryce and M. Murugesu, New J. Chem., 2015, 39, 7147
    DOI: 10.1039/C5NJ01125F

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