Jump to main content
Jump to site search

Issue 5, 2015
Previous Article Next Article

Upgrading biogenic furans: blended C10–C12 platform chemicals via lyase-catalyzed carboligations and formation of novel C12 – choline chloride-based deep-eutectic-solvents

Author affiliations

Abstract

Benzaldehyde lyase (BAL) results in an efficient biocatalyst for the umpolung carboligation of furfural, HMF, and mixtures of them, leading to blended C10–C12 platform chemicals. Subsequently, the mixing and gentle heating (<100 °C) of the formed hydroxy-ketone with choline chloride leads to the formation of a novel biomass-derived deep-eutectic-solvent.

Graphical abstract: Upgrading biogenic furans: blended C10–C12 platform chemicals via lyase-catalyzed carboligations and formation of novel C12 – choline chloride-based deep-eutectic-solvents

Back to tab navigation

Supplementary files

Publication details

The article was received on 11 Feb 2015, accepted on 02 Mar 2015 and first published on 09 Mar 2015


Article type: Communication
DOI: 10.1039/C5GC00342C
Author version
available:
Download author version (PDF)
Citation: Green Chem., 2015,17, 2714-2718
  • Open access: Creative Commons BY license
  •   Request permissions

    Upgrading biogenic furans: blended C10–C12 platform chemicals via lyase-catalyzed carboligations and formation of novel C12 – choline chloride-based deep-eutectic-solvents

    J. Donnelly, C. R. Müller, L. Wiermans, C. J. Chuck and P. Domínguez de María, Green Chem., 2015, 17, 2714
    DOI: 10.1039/C5GC00342C

    This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements