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Volume 184, 2015
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Optical micro-spectroscopy of single metallic nanoparticles: quantitative extinction and transient resonant four-wave mixing

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Abstract

We report a wide-field imaging method to rapidly and quantitatively measure the optical extinction cross-section σext (also polarisation resolved) of a large number of individual gold nanoparticles, for statistically-relevant single particle analysis. We demonstrate a sensitivity of 5 nm2 in σext, enabling detection of single 5 nm gold nanoparticles with total acquisition times in the 1 min range. Moreover, we have developed an analytical model of the polarisation resolved σext, which enabled us to extract geometrical particle aspect ratios from the measured σext. Using this method, we have characterized a large number of nominally-spherical gold nanoparticles in the 10–100 nm size range. Furthermore, the method provided measurements of in-house fabricated nanoparticle conjugates, allowing distinction of individual dimers from single particles and larger aggregates. The same particle conjugates were investigated correlatively by phase-resolved transient resonant four-wave mixing micro-spectroscopy. A direct comparison of the phase-resolved response between single gold nanoparticles and dimers highlighted the promise of the four-wave mixing technique for sensing applications with dimers as plasmon rulers.

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Publication details

The article was received on 14 May 2015, accepted on 29 May 2015 and first published on 29 May 2015


Article type: Paper
DOI: 10.1039/C5FD00079C
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Citation: Faraday Discuss., 2015,184, 305-320
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    Optical micro-spectroscopy of single metallic nanoparticles: quantitative extinction and transient resonant four-wave mixing

    L. Payne, G. Zoriniants, F. Masia, K. P. Arkill, P. Verkade, D. Rowles, W. Langbein and P. Borri, Faraday Discuss., 2015, 184, 305
    DOI: 10.1039/C5FD00079C

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