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Issue 48, 2015
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A room temperature spin crossover ionic liquid

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Abstract

Two new paramagnetic ionic liquids (ILs) comprising a mononuclear iron(III) or manganese(III) complex cation, charge balanced by a dicyanamide anion are reported which show a range of spin states. Both are liquids at room temperature and the Fe(III) based IL exhibits a spin crossover close to 300 K. The spin crossover profile is independent of the solvation, and is both air and moisture stable.

Graphical abstract: A room temperature spin crossover ionic liquid

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Publication details

The article was received on 30 Oct 2015, accepted on 13 Nov 2015 and first published on 13 Nov 2015


Article type: Communication
DOI: 10.1039/C5DT04264J
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2015,44, 20839-20842
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    A room temperature spin crossover ionic liquid

    A. J. Fitzpatrick, H. M. O'Connor and G. G. Morgan, Dalton Trans., 2015, 44, 20839
    DOI: 10.1039/C5DT04264J

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