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Issue 47, 2015
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A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand

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Abstract

The encapsulation of a fluoride ion in a trigonal prismatic CuII6-pyrazolato cage results in a small expansion of the Cu6-host. The structural, electronic and magnetic features of the Cu6-complex, containing an endohedral fluoride in the rare μ6-F coordination mode, are compared with those of the parent complex with a vacant Cu6-cage.

Graphical abstract: A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand

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Publication details

The article was received on 06 Oct 2015, accepted on 30 Oct 2015 and first published on 04 Nov 2015


Article type: Paper
DOI: 10.1039/C5DT03892H
Citation: Dalton Trans., 2015,44, 20685-20691
  • Open access: Creative Commons BY-NC license
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    A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand

    L. Mathivathanan, K. Al-Ameed, K. Lazarou, Z. Trávníček, Y. Sanakis, R. Herchel, J. E. McGrady and R. G. Raptis, Dalton Trans., 2015, 44, 20685
    DOI: 10.1039/C5DT03892H

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