Reduction of Eu3+ due to a change of the topological structure of the BO3 unit in borate glass

Su Zhang; Ran Pang; Da Li; Jipeng Fu; Yonglei Jia; Haifeng Li; Wenzhi Sun; Lihong Jiang; Chengyu Li

doi:10.1039/C5DT03606B

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Reduction of Eu³⁺ due to a change of the topological structure of the BO₃ unit in borate glass†

Su Zhang,^a Ran Pang,^a Da Li,^a Jipeng Fu,^ab Yonglei Jia,^ab Haifeng Li,^ab Wenzhi Sun,^ab Lihong Jiang*^a and Chengyu Li*^a

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* Corresponding authors

^a State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China
E-mail: lhjiang@ciac.ac.cn, cyli@ciac.ac.cn

^b University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

Adjusting and controlling an ion’s chemical state has always been a focus of researchers’ attention. Herein, an intense long-lasting phosphorescence of Eu²⁺ is obtained without any sacrificial reductant. The remarkable self-reducing process and the unique luminescence properties stem from a variation of the topological structure of the BO₃ triangle.

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Article information

DOI: https://doi.org/10.1039/C5DT03606B
Article type: Communication
Submitted: 15 Sep 2015
Accepted: 17 Sep 2015
First published: 21 Sep 2015

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Dalton Trans., 2015,44, 17916-17919

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Reduction of Eu³⁺ due to a change of the topological structure of the BO₃ unit in borate glass

S. Zhang, R. Pang, D. Li, J. Fu, Y. Jia, H. Li, W. Sun, L. Jiang and C. Li, Dalton Trans., 2015, 44, 17916 DOI: 10.1039/C5DT03606B

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Dalton Transactions