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Issue 35, 2015
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Novel phenanthroline–diaryldiazadiene ligands with heteroditopic coordination spheres

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Abstract

1,10-Phenanthroline-5,6-diaryldiazadienes are key structures for the development of novel heterodinuclear photocatalysts and for the construction of extended heterocycles of potential biological use. Herein, the first examples of this compound family are presented together with a wide range of initial reactivity studies. Synthetic strategies are presented to access the two first derivatives of the ligand and to accomplish subsequent metal coordination to the phenanthroline sphere.

Graphical abstract: Novel phenanthroline–diaryldiazadiene ligands with heteroditopic coordination spheres

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Publication details

The article was received on 23 Jun 2015, accepted on 23 Jul 2015 and first published on 23 Jul 2015


Article type: Communication
DOI: 10.1039/C5DT02383A
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2015,44, 15404-15407
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    Novel phenanthroline–diaryldiazadiene ligands with heteroditopic coordination spheres

    D. Sorsche, C. Pehlken, C. Baur, S. Rommel, K. Kastner, C. Streb and S. Rau, Dalton Trans., 2015, 44, 15404
    DOI: 10.1039/C5DT02383A

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