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Issue 37, 2015
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Single-molecule magnet behaviour in polynuclear assembly of trivalent cerium ions with polyoxomolybdates

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Abstract

An isopolyoxomolybdate-based POM is coordinated to trivalent cerium ions to afford a hybrid complex namely, [Ce(dmso)8][Ce(η2-NO3)2(dmso)4(α-Mo8O26)0.5][Mo6O19]. The original electrostatic environment created around the CeIII by its coordination to the isopolyoxomolybdate core induces complex single-molecule magnet behavior.

Graphical abstract: Single-molecule magnet behaviour in polynuclear assembly of trivalent cerium ions with polyoxomolybdates

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Publication details

The article was received on 23 Jun 2015, accepted on 20 Jul 2015 and first published on 20 Jul 2015


Article type: Paper
DOI: 10.1039/C5DT02377G
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Citation: Dalton Trans., 2015,44, 16458-16464
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    Single-molecule magnet behaviour in polynuclear assembly of trivalent cerium ions with polyoxomolybdates

    A. B. Khélifa, M. S. Belkhiria, G. Huang, S. Freslon, O. Guillou and K. Bernot, Dalton Trans., 2015, 44, 16458
    DOI: 10.1039/C5DT02377G

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