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Issue 25, 2015
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Thermochromism and switchable paramagnetism of cobalt(II) in thiocyanate ionic liquids

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Abstract

Temperature-dependent switching of paramagnetism of a cobalt(II) complex is observed in an ionic liquid solution. Paramagnetic and thermochromic switching occur simultaneously due to a reversible change in coordination. This reversible switching is possible in the ionic liquid solution, which enables mobility of thiocyanate anions by remaining mobile at low temperatures and acts as an anion reservoir.

Graphical abstract: Thermochromism and switchable paramagnetism of cobalt(ii) in thiocyanate ionic liquids

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Publication details

The article was received on 15 May 2015, accepted on 02 Jun 2015 and first published on 02 Jun 2015


Article type: Communication
DOI: 10.1039/C5DT01829C
Citation: Dalton Trans., 2015,44, 11286-11289
  • Open access: Creative Commons BY license
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    Thermochromism and switchable paramagnetism of cobalt(II) in thiocyanate ionic liquids

    S. J. Osborne, S. Wellens, C. Ward, S. Felton, R. M. Bowman, K. Binnemans, M. Swadźba-Kwaśny, H. Q. N. Gunaratne and P. Nockemann, Dalton Trans., 2015, 44, 11286
    DOI: 10.1039/C5DT01829C

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