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Issue 30, 2015
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Mechano-induced reversible colour and luminescence switching of a gold(I)–diphosphine complex

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Abstract

A gold(I)–diphosphine simultaneously exhibits reversible mechanochromism and mechanochromic luminescence. The mechanical grinding can trigger a transformation from a neutral mononuclear structure exhibiting white colour and blue photoluminescence to an ionic dinuclear structure with intramolecular aurophilic interactions exhibiting yellow colour and red emission.

Graphical abstract: Mechano-induced reversible colour and luminescence switching of a gold(i)–diphosphine complex

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Publication details

The article was received on 13 May 2015, accepted on 26 Jun 2015 and first published on 26 Jun 2015


Article type: Communication
DOI: 10.1039/C5DT01795E
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2015,44, 13455-13459
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    Mechano-induced reversible colour and luminescence switching of a gold(I)–diphosphine complex

    P. Baranyai, G. Marsi, C. Jobbágy, A. Domján, L. Oláh and A. Deák, Dalton Trans., 2015, 44, 13455
    DOI: 10.1039/C5DT01795E

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