Issue 30, 2015

Mechano-induced reversible colour and luminescence switching of a gold(i)–diphosphine complex

Abstract

A gold(I)–diphosphine simultaneously exhibits reversible mechanochromism and mechanochromic luminescence. The mechanical grinding can trigger a transformation from a neutral mononuclear structure exhibiting white colour and blue photoluminescence to an ionic dinuclear structure with intramolecular aurophilic interactions exhibiting yellow colour and red emission.

Graphical abstract: Mechano-induced reversible colour and luminescence switching of a gold(i)–diphosphine complex

Supplementary files

Article information

Article type
Communication
Submitted
13 May 2015
Accepted
26 Jun 2015
First published
26 Jun 2015

Dalton Trans., 2015,44, 13455-13459

Author version available

Mechano-induced reversible colour and luminescence switching of a gold(I)–diphosphine complex

P. Baranyai, G. Marsi, C. Jobbágy, A. Domján, L. Oláh and A. Deák, Dalton Trans., 2015, 44, 13455 DOI: 10.1039/C5DT01795E

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