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Issue 39, 2015
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An overview of selected current approaches to the characterization of aqueous inorganic clusters

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Abstract

This Perspective article highlights some of the traditional and non-traditional analytical tools that are presently used to characterize aqueous inorganic nanoscale clusters and polyoxometalate ions. The techniques discussed in this article include nuclear magnetic resonance spectroscopy (NMR), small angle X-ray scattering (SAXS), dynamic and phase analysis light scattering (DLS and PALS), Raman spectroscopy, and quantum mechanical computations (QMC). For each method we briefly describe how it functions and illustrate how these techniques are used to study cluster species in the solid state and in solution through several representative case studies. In addition to highlighting the utility of these techniques, we also discuss limitations of each approach and measures that can be applied to circumvent such limits as it pertains to aqueous inorganic cluster characterization.

Graphical abstract: An overview of selected current approaches to the characterization of aqueous inorganic clusters

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Publication details

The article was received on 08 Apr 2015, accepted on 23 Jun 2015 and first published on 27 Jul 2015


Article type: Perspective
DOI: 10.1039/C5DT01268F
Citation: Dalton Trans., 2015,44, 16982-17006
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    An overview of selected current approaches to the characterization of aqueous inorganic clusters

    M. N. Jackson, M. K. Kamunde-Devonish, B. A. Hammann, L. A. Wills, L. B. Fullmer, S. E. Hayes, P. H.-Y. Cheong, W. H. Casey, M. Nyman and D. W. Johnson, Dalton Trans., 2015, 44, 16982
    DOI: 10.1039/C5DT01268F

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