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Issue 24, 2015
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Direct synthesis of a {CoIII6FeIII6} dodecanuclear complex, revealing an unprecedented molecular structure type

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Abstract

A novel heterometallic Co6Fe6 Schiff base complex, possessing an unprecedented {M12(μ-X)22} branched structure (according to the search via the Cambridge Structural Database), has been prepared using the “direct synthesis” approach and characterized by single crystal X-ray diffraction and magnetometry.

Graphical abstract: Direct synthesis of a {CoIII6FeIII6} dodecanuclear complex, revealing an unprecedented molecular structure type

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Publication details

The article was received on 23 Mar 2015, accepted on 09 Apr 2015 and first published on 20 May 2015


Article type: Communication
DOI: 10.1039/C5DT01149C
Citation: Dalton Trans., 2015,44, 10918-10922
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    Direct synthesis of a {CoIII6FeIII6} dodecanuclear complex, revealing an unprecedented molecular structure type

    E. N. Chygorin, V. N. Kokozay, I. V. Omelchenko, O. V. Shishkin, J. Titiš, R. Boča and D. S. Nesterov, Dalton Trans., 2015, 44, 10918
    DOI: 10.1039/C5DT01149C

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