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Issue 34, 2015
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Regulation of a cerium(IV)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexes

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Abstract

A composite containing a liposome and a lipophilic ruthenium complex was synthesized to regulate an O2 evolution reaction using cerium(IV) ammonium nitrate as an oxidizing reagent. We found that the surrounding environment of the reaction centre is an important factor for controlling the O2 evolution catalytic reaction. We successfully regulated the reaction activity using the linker length of the lipophilic ligand and using the head groups of the phospholipid component.

Graphical abstract: Regulation of a cerium(iv)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexes

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Publication details

The article was received on 24 Feb 2015, accepted on 29 Apr 2015 and first published on 29 Apr 2015


Article type: Communication
DOI: 10.1039/C5DT00793C
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2015,44, 15126-15129
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    Regulation of a cerium(IV)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexes

    T. Koshiyama, N. Kanda, K. Iwata, M. Honjo, S. Asada, T. Hatae, Y. Tsuji, M. Yoshida, M. Okamura, R. Kuga, S. Masaoka and M. Ohba, Dalton Trans., 2015, 44, 15126
    DOI: 10.1039/C5DT00793C

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