Issue 17, 2015
From the journal:

Dalton Transactions

A one-dimensional coordination polymer based on Cu3-oximato metallacrowns bridged by benzene-1,4-dicarboxylato ligands: structure and magnetic properties†

Lilia Croitor,*a   Eduard B. Coropceanu,b   Oleg Petuhov,b   Karl W. Krämer,c   Svetlana G. Baca,a   Shi-Xia Liu,c   Silvio Decurtinsc  and  Marina S. Fonaria  

* Corresponding authors

a Institute of Applied Physics, Academy of Sciences of R. Moldova, Academy str., Chisinau, Moldova
E-mail: croitor.lilia@gmail.com
Fax: +373 22 725887
Tel: +373 22 738154

b Institute of Chemistry, Academy of Sciences of R. Moldova, Academy str., Chisinau, Moldova

c Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, 3012 Bern, Switzerland

Abstract

A one-dimensional linear coordination polymer {[Cu3(μ3-OH)(2-pyao)3(bdc)]·6(H2O)}n (1) composed of trinuclear [Cu3(μ3-OH)(2-pyao)3]2+ metallacrown cores bridged by bis-carboxylato linkers has been obtained by treatment of copper(II) fluoride with pyridine-2-aldoxime (2-pyaoH) ligand and benzene-1,4-dicarboxylic acid (H2bdc). Magnetic susceptibility measurements show strong antiferromagnetic interactions between Cu(II) centers within the trinuclear metallacrown core with J = −430 cm−1.

Graphical abstract: A one-dimensional coordination polymer based on Cu3-oximato metallacrowns bridged by benzene-1,4-dicarboxylato ligands: structure and magnetic properties

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5DT00533G
Article type
Paper
Submitted
05 Feb 2015
Accepted
17 Mar 2015
First published
20 Mar 2015
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2015,44, 7896-7902

Permissions

Request permissions

A one-dimensional coordination polymer based on Cu3-oximato metallacrowns bridged by benzene-1,4-dicarboxylato ligands: structure and magnetic properties

L. Croitor, E. B. Coropceanu, O. Petuhov, K. W. Krämer, S. G. Baca, S. Liu, S. Decurtins and M. S. Fonari, Dalton Trans., 2015, 44, 7896 DOI: 10.1039/C5DT00533G

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements