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Issue 20, 2015
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Spin-crossover behaviors in solvated cobalt(II) compounds

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Abstract

Two solvated cobalt(II) terpyridine complexes, [Co(MeO-terpy)2](BF4)2·H2O (1·H2O) and [Co(MeO-terpy)2](BF4)2·acetone (1·acetone) were prepared. Annealing each of these complexes resulted in the formation of two desolvated species, 1 and 1′, respectively. 1·H2O and 1 exhibited two-step and gradual SCO. The compound 1·acetone has high-spin at all temperatures and 1′ undergoes a reverse spin transition due to a phase change.

Graphical abstract: Spin-crossover behaviors in solvated cobalt(ii) compounds

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Publication details

The article was received on 07 Dec 2014, accepted on 23 Dec 2014 and first published on 07 Jan 2015


Article type: Communication
DOI: 10.1039/C4DT03743J
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2015,44, 9345-9348
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    Spin-crossover behaviors in solvated cobalt(II) compounds

    S. Hayami, M. Nakaya, H. Ohmagari, A. S. Alao, M. Nakamura, R. Ohtani, R. Yamaguchi, T. Kuroda-Sowa and J. K. Clegg, Dalton Trans., 2015, 44, 9345
    DOI: 10.1039/C4DT03743J

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