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Issue 2, 2015
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Formation of a novel ferromagnetic end-to-end cyanate bridged homochiral helical copper(II) Schiff base complex via spontaneous symmetry breaking

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Abstract

A homochiral helical coordination polymer of copper(II) has been synthesized using achiral precursors via spontaneous symmetry breaking and has been confirmed by single crystal X-ray diffraction and solid-state CD spectroscopy. The variable temperature magnetic measurements indicate the presence of weak ferromagnetic exchange interactions mediated by end-to-end cyanate bridges (J = +0.12 cm−1).

Graphical abstract: Formation of a novel ferromagnetic end-to-end cyanate bridged homochiral helical copper(ii) Schiff base complex via spontaneous symmetry breaking

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Publication details

The article was received on 14 Oct 2014, accepted on 31 Oct 2014 and first published on 04 Nov 2014


Article type: Communication
DOI: 10.1039/C4DT03166K
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2015,44, 493-497
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    Formation of a novel ferromagnetic end-to-end cyanate bridged homochiral helical copper(II) Schiff base complex via spontaneous symmetry breaking

    A. Bhattacharyya, B. N. Ghosh, S. Herrero, K. Rissanen, R. Jiménez-Aparicio and S. Chattopadhyay, Dalton Trans., 2015, 44, 493
    DOI: 10.1039/C4DT03166K

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