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Issue 3, 2015
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P,C-bond cleavage in the ligand sphere of a nickel(II) complex

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Abstract

Reacting nickel(II)perchlorate with a bidentate P,N-ligand in methanol leads to P,C-bond cleavage and gives a five-coordinate nickel complex wherein the nickel(II) site is coordinated by a tridentate P,N,P-ligand and a bidentate N,C-ligand. The carbanion of the latter is the result of the P,C-bond cleaving process. The diamagnetic nickel(II) complex was characterized by means of elemental analysis, NMR spectroscopy, cyclic voltammetry and X-ray structure analysis.

Graphical abstract: P,C-bond cleavage in the ligand sphere of a nickel(ii) complex

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Publication details

The article was received on 18 Jul 2014, accepted on 13 Oct 2014, published on 14 Oct 2014 and first published online on 14 Oct 2014


Article type: Paper
DOI: 10.1039/C4DT02158D
Citation: Dalton Trans., 2015,44, 1317-1322
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    P,C-bond cleavage in the ligand sphere of a nickel(II) complex

    S. P. Walg, A. D. Schmidt, M. Schmitz, S. Farsadpour, J. Lang, M. Niebergall, Y. Sun, P. W. Roesky, G. Niedner-Schatteburg and W. R. Thiel, Dalton Trans., 2015, 44, 1317
    DOI: 10.1039/C4DT02158D

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