Jump to main content
Jump to site search

Issue 21, 2015
Previous Article Next Article

High-resolution X-ray absorption spectroscopy of iron carbonyl complexes

Author affiliations

Abstract

We apply high-energy-resolution fluorescence-detected (HERFD) X-ray absorption near-edge spectroscopy (XANES) to study iron carbonyl complexes. Mono-, bi-, and tri-nuclear carbonyl complexes and pure carbonyl complexes as well as carbonyl complexes containing hydrocarbon ligands are considered. The HERFD-XANES spectra reveal multiple pre-edge peaks with individual signatures for each complex, which could not be detected previously with conventional XANES spectroscopy. These peaks are assigned and analysed with the help of TD-DFT calculations. We demonstrate that the pre-edge peaks can be used to distinguish the different types of iron–iron interactions in carbonyl complexes. This opens up new possibilities for applying HERFD-XANES spectroscopy to probe the electronic structure of iron catalysts.

Graphical abstract: High-resolution X-ray absorption spectroscopy of iron carbonyl complexes

Back to tab navigation

Supplementary files

Publication details

The article was received on 19 Feb 2015, accepted on 29 Apr 2015 and first published on 29 Apr 2015


Article type: Paper
DOI: 10.1039/C5CP01045D
Citation: Phys. Chem. Chem. Phys., 2015,17, 13937-13948
  • Open access: Creative Commons BY-NC license
  •   Request permissions

    High-resolution X-ray absorption spectroscopy of iron carbonyl complexes

    A. J. Atkins, M. Bauer and C. R. Jacob, Phys. Chem. Chem. Phys., 2015, 17, 13937
    DOI: 10.1039/C5CP01045D

    This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements