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Issue 6, 2015
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The influence of bridge-reduced state levels on the electron transfer within the 2,7-dinitroanthracene radical anion

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Abstract

Optical and EPR spectroscopy show that the 2,7-dinitroanthracene radical anion has an (apparent) electronic coupling much higher than either its N,N distance or its non-Kekule substitution would suggest. The results can only be explained if a low-lying bridge redox state is influencing the electron transfer.

Graphical abstract: The influence of bridge-reduced state levels on the electron transfer within the 2,7-dinitroanthracene radical anion

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The article was received on 20 Nov 2014, accepted on 06 Jan 2015 and first published on 06 Jan 2015


Article type: Communication
DOI: 10.1039/C4CP05404K
Author version available: Download Author version (PDF)
Citation: Phys. Chem. Chem. Phys., 2015,17, 4038-4041
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    The influence of bridge-reduced state levels on the electron transfer within the 2,7-dinitroanthracene radical anion

    J. P. Telo and Á. Moneo, Phys. Chem. Chem. Phys., 2015, 17, 4038
    DOI: 10.1039/C4CP05404K

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