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Issue 22, 2015
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Green synthesis of zirconium-MOFs

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Abstract

The synthesis of Zr-MOFs under green, industrially feasible conditions was investigated. Two new compounds with bcu-topology and the fluorinated analogue of UiO-66 exhibiting fcu-topology were obtained and characterised. All products exhibit permanent porosity. In the bcu-frameworks the interaction with sulfate anions apparently induces an unusual eightfold connectivity of the Zr cluster.

Graphical abstract: Green synthesis of zirconium-MOFs

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Publication details

The article was received on 29 Mar 2015, accepted on 23 Apr 2015 and first published on 30 Apr 2015


Article type: Communication
DOI: 10.1039/C5CE00618J
Citation: CrystEngComm, 2015,17, 4070-4074
  • Open access: Creative Commons BY license
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    Green synthesis of zirconium-MOFs

    H. Reinsch, B. Bueken, F. Vermoortele, I. Stassen, A. Lieb, K. Lillerud and D. De Vos, CrystEngComm, 2015, 17, 4070
    DOI: 10.1039/C5CE00618J

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