Jump to main content
Jump to site search

Issue 1, 2016
Previous Article Next Article

Rhenium(V)–oxo corrolazines: isolating redox-active ligand reactivity

Author affiliations

Abstract

The synthesis of the first example of a third-row metallocorrolazine characterized by single crystal X-ray diffraction is reported. This ReV(O) porphyrinoid complex shows an exclusively ligand-based reactivity with strong acids and oxidizing agents. The one-electron oxidized π-radical-cation complex is capable of H-atom abstraction.

Graphical abstract: Rhenium(v)–oxo corrolazines: isolating redox-active ligand reactivity

Back to tab navigation

Supplementary files

Publication details

The article was received on 22 Sep 2015, accepted on 15 Oct 2015 and first published on 28 Oct 2015


Article type: Communication
DOI: 10.1039/C5CC07956J
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2016,52, 167-170
  •   Request permissions

    Rhenium(V)–oxo corrolazines: isolating redox-active ligand reactivity

    J. P. T. Zaragoza, M. A. Siegler and D. P. Goldberg, Chem. Commun., 2016, 52, 167
    DOI: 10.1039/C5CC07956J

Search articles by author

Spotlight

Advertisements