Issue 55, 2015
From the journal:

Chemical Communications

Orthogonal breaking and forming of dynamic covalent imine and disulfide bonds in aqueous solution†

Michael E. Bracchia  and  David A. Fulton*a  

* Corresponding authors

a A Chemical Nanoscience Laboratory, School of Chemistry, Newcastle University, Bedson Building, Newcastle Upon Tyne, UK
E-mail: david.fulton@ncl.ac.uk
Fax: +44 (0)191 208 6929
Tel: +44 (0)191 208 7065

Abstract

Orthogonal bond-breaking and forming of dynamic covalent disulfide and imine bonds in aqueous solution is demonstrated. Through judicious choice of reaction partners and conditions, it is possible to cleave and reform selectively these bonds in the presence of each other in the absence of unwanted competing processes.

Graphical abstract: Orthogonal breaking and forming of dynamic covalent imine and disulfide bonds in aqueous solution

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Article information

DOI
https://doi.org/10.1039/C5CC02716K
Article type
Communication
Submitted
01 Apr 2015
Accepted
05 Jun 2015
First published
05 Jun 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 11052-11055

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Orthogonal breaking and forming of dynamic covalent imine and disulfide bonds in aqueous solution

M. E. Bracchi and D. A. Fulton, Chem. Commun., 2015, 51, 11052 DOI: 10.1039/C5CC02716K

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