Issue 37, 2015
From the journal:

Chemical Communications

Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C–H silylation†

Takanori Shibata,*ab   Tsubasa Shizunoa  and  Tomoya Sasakia  

* Corresponding authors

a Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555, Japan
E-mail: tshibata@waseda.jp
Fax: (+81) 3-5286-8098

b JST, ACT-C, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

Abstract

The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp2 C–H bond of ferrocene with a Si–H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.

Graphical abstract: Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C–H silylation

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Article information

DOI
https://doi.org/10.1039/C5CC00723B
Article type
Communication
Submitted
26 Jan 2015
Accepted
06 Feb 2015
First published
06 Feb 2015

Chem. Commun., 2015,51, 7802-7804

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Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C–H silylation

T. Shibata, T. Shizuno and T. Sasaki, Chem. Commun., 2015, 51, 7802 DOI: 10.1039/C5CC00723B

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