Issue 7, 2015
From the journal:

Chemical Communications

Controlled access to a heterometallic N-heterocyclic carbene helicate†

Qiaoqiao Tenga  and  Han Vinh Huynh*a  

* Corresponding authors

a Department of Chemistry, National University of Singapore, 3 Science Drive 3, Republic of Singapore
E-mail: chmhhv@nus.edu.sg

Abstract

Metallation of a pentadentate diNHC proligand bearing a dipropyl-pyridine-2,6-dicarboxamide with silver and gold affords mono- and dinuclear, double-stranded bis(NHC) complexes as useful building blocks for metallo-supramolecules. The digold(I) complex acts as a metallo-bis(pincer) ligand to furnish the first example of an organometallic NHC-helicate upon coordination to cobalt.

Graphical abstract: Controlled access to a heterometallic N-heterocyclic carbene helicate

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Article information

DOI
https://doi.org/10.1039/C4CC08270B
Article type
Communication
Submitted
20 Oct 2014
Accepted
28 Nov 2014
First published
01 Dec 2014

Chem. Commun., 2015,51, 1248-1251

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Controlled access to a heterometallic N-heterocyclic carbene helicate

Q. Teng and H. V. Huynh, Chem. Commun., 2015, 51, 1248 DOI: 10.1039/C4CC08270B

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