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Issue 1, 2015
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Palladium catalyzed Csp2–H activation for direct aryl hydroxylation: the unprecedented role of 1,4-dioxane as a source of hydroxyl radicals

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Abstract

A novel strategy for direct aryl hydroxylation via Pd-catalysed Csp2–H activation through an unprecedented hydroxyl radical transfer from 1,4-dioxane, used as a solvent, is reported with bio relevant and sterically hindered heterocycles and various acyclic functionalities as versatile directing groups.

Graphical abstract: Palladium catalyzed Csp2–H activation for direct aryl hydroxylation: the unprecedented role of 1,4-dioxane as a source of hydroxyl radicals

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Publication details

The article was received on 31 Aug 2014, accepted on 03 Nov 2014 and first published on 04 Nov 2014


Article type: Communication
DOI: 10.1039/C4CC06864E
Citation: Chem. Commun., 2015,51, 191-194
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    Palladium catalyzed Csp2–H activation for direct aryl hydroxylation: the unprecedented role of 1,4-dioxane as a source of hydroxyl radicals

    K. Seth, M. Nautiyal, P. Purohit, N. Parikh and A. K. Chakraborti, Chem. Commun., 2015, 51, 191
    DOI: 10.1039/C4CC06864E

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