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Issue 98, 2015
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N-Heterocyclic carbene ligands bearing poly(ethylene glycol) chains: effect of the chain length on palladium-catalyzed coupling reactions employing aryl chlorides

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Abstract

N-Heterocyclic carbenes bearing poly(ethylene glycol) chains of different lengths have been designed and employed as ligands in palladium-catalyzed coupling reactions. The catalyst system having longer chains was found to be highly efficient for Suzuki–Miyaura coupling and borylation reactions employing aryl chlorides under mild reaction conditions.

Graphical abstract: N-Heterocyclic carbene ligands bearing poly(ethylene glycol) chains: effect of the chain length on palladium-catalyzed coupling reactions employing aryl chlorides

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Publication details

The article was received on 10 Sep 2015, accepted on 05 Oct 2015 and first published on 08 Oct 2015


Article type: Communication
DOI: 10.1039/C5CC07588B
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2015,51, 17382-17385
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    N-Heterocyclic carbene ligands bearing poly(ethylene glycol) chains: effect of the chain length on palladium-catalyzed coupling reactions employing aryl chlorides

    T. Fujihara, T. Yoshikawa, M. Satou, H. Ohta, J. Terao and Y. Tsuji, Chem. Commun., 2015, 51, 17382
    DOI: 10.1039/C5CC07588B

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