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Issue 95, 2015
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Diversity-oriented synthesis of tetrathia[8]circulenes by sequential C–H borylation and annulation

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Abstract

We have succeeded in the diversity-oriented synthesis of tetrathia[8]circulenes by sequential C–H borylation and annulation from cyclic tetrathiophene, and time-resolved microwave conductivity studies have proved that the intrinsic hole mobilities of tetrathia[8]circulenes are dependent on the chain length of the alkyl substituents at the peripheral positions.

Graphical abstract: Diversity-oriented synthesis of tetrathia[8]circulenes by sequential C–H borylation and annulation

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Publication details

The article was received on 18 Aug 2015, accepted on 29 Sep 2015 and first published on 29 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC06921A
Citation: Chem. Commun., 2015,51, 16944-16947
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    Diversity-oriented synthesis of tetrathia[8]circulenes by sequential C–H borylation and annulation

    S. Kato, Y. Serizawa, D. Sakamaki, S. Seki, Y. Miyake and H. Shinokubo, Chem. Commun., 2015, 51, 16944
    DOI: 10.1039/C5CC06921A

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