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Issue 97, 2015
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Are the orientation and bond strength of the RCO2⋯M link key factors for ultrafast electron transfers?

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Abstract

The photo-induced electron transfers in the “straight up” ionic assemblies [Pd32+]⋯MCP and [Pd32+]⋯DCP⋯[Pd32+] ([Pd32+]* → MCP or DCP) are ultrafast (<85 fs) indicating that it is not necessary to have a strong coordination bond or a bent geometry to obtain fast electron injection in porphyrin-containing DSSCs.

Graphical abstract: Are the orientation and bond strength of the RCO2−⋯M link key factors for ultrafast electron transfers?

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The article was received on 17 Aug 2015, accepted on 28 Sep 2015 and first published on 28 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC06779K
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Citation: Chem. Commun., 2015,51, 17305-17308
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    Are the orientation and bond strength of the RCO2⋯M link key factors for ultrafast electron transfers?

    P. Luo, P. Karsenti, G. Brisard, B. Marsan and P. D. Harvey, Chem. Commun., 2015, 51, 17305
    DOI: 10.1039/C5CC06779K

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