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Issue 95, 2015
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Asymmetric bromine–lithium exchange: on the importance of both the diamine ligand and the organolithium reagent

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Abstract

The asymmetric bromine–lithium exchange on a series of prochiral biphenyls was investigated. As in many asymmetric organolithium reactions, the chiral ligand (here a diamine) was considered to be the enantiocontrolling element. We show here that the organolithium reagent also plays an important role.

Graphical abstract: Asymmetric bromine–lithium exchange: on the importance of both the diamine ligand and the organolithium reagent

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Publication details

The article was received on 01 Sep 2015, accepted on 29 Sep 2015 and first published on 29 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC06548H
Citation: Chem. Commun., 2015,51, 16912-16915
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    Asymmetric bromine–lithium exchange: on the importance of both the diamine ligand and the organolithium reagent

    J. Praz, J. Graff, L. Egger, L. Guénée, S. Wagschal, E. P. Kündig and A. Alexakis, Chem. Commun., 2015, 51, 16912
    DOI: 10.1039/C5CC06548H

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