Issue 89, 2015
From the journal:

Chemical Communications

Visible-light, photoredox catalyzed, oxidative hydroxylation of arylboronic acids using a metal–organic framework containing tetrakis(carboxyphenyl)porphyrin groups†

Takashi Toyao,a   Nana Ueno,a   Kenta Miyahara,a   Yasunori Matsui,ab   Tae-Ho Kim,c   Yu Horiuchi,*a   Hiroshi Ikedaab  and  Masaya Matsuoka*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan
E-mail: horiuchi@chem.osakafu-u.ac.jp, matsumac@chem.osakafu-u.ac.jp

b The Research Institute for Molecular Electronic Devices (RIMED), Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan

c Division of Mechanics and ICT Convergence Engineering, Sun Moon University, GalSan-Ri, Tangjung-Myon, Asan Chungnam 336708, Republic of Korea

Abstract

A Zr-based metal–organic framework with tetrakis(carboxyphenyl)porphyrin groups (Zr-MOF-TCPP: MOF-525) has been utilized as a photoredox catalyst to promote oxidative hydroxylation of arylboronic acids under green LED light irradiation. Zr-MOF-TCPP displays a superior catalytic activity for this process over the corresponding homogeneous catalyst (H4TCPP).

Graphical abstract: Visible-light, photoredox catalyzed, oxidative hydroxylation of arylboronic acids using a metal–organic framework containing tetrakis(carboxyphenyl)porphyrin groups

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Article information

DOI
https://doi.org/10.1039/C5CC06163F
Article type
Communication
Submitted
23 Jul 2015
Accepted
09 Sep 2015
First published
10 Sep 2015

Chem. Commun., 2015,51, 16103-16106

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Visible-light, photoredox catalyzed, oxidative hydroxylation of arylboronic acids using a metal–organic framework containing tetrakis(carboxyphenyl)porphyrin groups

T. Toyao, N. Ueno, K. Miyahara, Y. Matsui, T. Kim, Y. Horiuchi, H. Ikeda and M. Matsuoka, Chem. Commun., 2015, 51, 16103 DOI: 10.1039/C5CC06163F

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