Two coronoid hydrocarbons, [3]- and [4]chrysaorene were synthesized from fluorenophane precursors using the fold-in strategy. [3]Chrysaorene is a bowl-shaped fragment of the C240-Ih fullerene, whereas [4]chrysaorene is planar and contains a unique large 24-membered internal ring. The chrysaorenes show geometry-dependent magnetic properties and are strongly fluorescent.
M. A. Majewski, T. Lis, J. Cybińska and M. Stępień, Chem. Commun., 2015, 51, 15094 DOI: 10.1039/C5CC06046J
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