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Issue 75, 2015
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Oxidative inactivation of NiFeSe hydrogenase

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Abstract

We propose a resolution to the paradox that spectroscopic studies of NiFeSe hydrogenase have not revealed any major signal attributable to NiIII states formed upon reaction with O2, despite the fact that two inactive states are formed upon either aerobic or anaerobic oxidation.

Graphical abstract: Oxidative inactivation of NiFeSe hydrogenase

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Publication details

The article was received on 16 Jul 2015, accepted on 29 Jul 2015 and first published on 30 Jul 2015


Article type: Communication
DOI: 10.1039/C5CC05930E
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2015,51, 14223-14226
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    Oxidative inactivation of NiFeSe hydrogenase

    P. Ceccaldi, M. C. Marques, V. Fourmond, I. C. Pereira and C. Léger, Chem. Commun., 2015, 51, 14223
    DOI: 10.1039/C5CC05930E

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