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Issue 78, 2015
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Differentially functionalized acyclic cucurbiturils: synthesis, self-assembly and CB[6]-induced allosteric guest binding

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Abstract

We report the synthesis of mono- and difunctionalized acyclic cucurbit[n]uril-type containers (1HA, 1HDA, 2HDA) which bear hexylammonium and hexanediammonium arms. The intra- and intermolecular assembly processes of 1HA, 1HDA, 2HDA as well as the ability of CB[n] to trigger allosteric host–guest binding toward guests 9–11 are presented.

Graphical abstract: Differentially functionalized acyclic cucurbiturils: synthesis, self-assembly and CB[6]-induced allosteric guest binding

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Publication details

The article was received on 13 Jul 2015, accepted on 11 Aug 2015 and first published on 13 Aug 2015


Article type: Communication
DOI: 10.1039/C5CC05803A
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2015,51, 14620-14623
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    Differentially functionalized acyclic cucurbiturils: synthesis, self-assembly and CB[6]-induced allosteric guest binding

    M. Zhang, D. Sigwalt and L. Isaacs, Chem. Commun., 2015, 51, 14620
    DOI: 10.1039/C5CC05803A

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