Issue 64, 2015

AgNO2-mediated cleavage of the N–N bond of sulfonylhydrazones and oxygen transfer: access to fulleroisoxazolines via radical cyclization with [60]fullerene

Abstract

An unprecedented AgNO2-mediated novel transformation of sulfonylhydrazones with [60]fullerene to various fulleroisoxazolines has been developed. The new chemistry of sulfonylhydrazones involving the cleavage of the N–N bond in synthetic application is first disclosed. Silver nitrite acts as the reaction initiator and the oxygen source in this unique transformation. This reaction is easy to perform, and exhibits a remarkably wide substrate scope under mild conditions.

Graphical abstract: AgNO2-mediated cleavage of the N–N bond of sulfonylhydrazones and oxygen transfer: access to fulleroisoxazolines via radical cyclization with [60]fullerene

Supplementary files

Article information

Article type
Communication
Submitted
15 Jun 2015
Accepted
03 Jul 2015
First published
03 Jul 2015

Chem. Commun., 2015,51, 12775-12778

AgNO2-mediated cleavage of the N–N bond of sulfonylhydrazones and oxygen transfer: access to fulleroisoxazolines via radical cyclization with [60]fullerene

T. Liu, J. Ma, D. Chao, P. Zhang, Q. Liu, L. Shi, Z. Zhang and G. Zhang, Chem. Commun., 2015, 51, 12775 DOI: 10.1039/C5CC04934B

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